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Reliable factory customized supply Dicyclopropyl ketone 1121-37-5
- Molecular Formula: C7H10O
- Molecular Weight: 110.156
- Appearance/Colour: clear colourless to yellowish liquid
- Vapor Pressure: 2.32mmHg at 25°C
- Melting Point: 44.0-44.5 °C
- Refractive Index: n20/D 1.467(lit.)
- Boiling Point: 161 °C at 760 mmHg
- Flash Point: 39.4 °C
- PSA: 17.07000
- Density: 1.174 g/cm3
- LogP: 1.37550
Dicyclopropyl ketone(Cas 1121-37-5) Usage
|
Preparation |
Preparation of Dicyclopropyl ketoneReaction: To a one liter three-necked flask fitted with a reflux condenser and a metal Hershberg stirrer there was added 600 ml. of 20% sodium hydroxide and 165g . (0.9mole) of 1,7 -dichloro-4-heptanone. The mixture was refluxed for 30 minutes with vigorous stirring, then steam distilled until the characteristic odor of dicyclopropyl ketone was absent from the distillate. The distillate was then saturated with potassium carbonate, the upper layer separated and the water layer extracted once with ether. The combined organic layers were dried over potassium carbonate. after removal of the ether there was dist illed 69g. (70%) of dicyclopropyl ketone, b.p . 69° at 20 mm, nD25 1.4648-1.4654. |
InChI:InChI=1/C7H10O/c8-7(5-1-2-5)6-3-4-6/h5-6H,1-4H2
1121-37-5 Relevant articles
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Russel,Malkus
, p. 160 (1967)
-
THIOCARBONYLS INTO CARBONYLS: EFFICIENT CONVERSION BY CLAY-SUPPORTED FERRIC NITRATE
Chalais, Stephane,Cornelis, Andre,Laszlo, Pierre,Mathy, Arthur
, p. 2327 - 2328 (1985)
A simple and inexpensive procedure is pr...
Electrochemical Reduction of Bis(α-bromocyclopropyl) Ketone
Fry, Albert J.,Andersson, Jan T.
, p. 1490 - 1492 (1981)
-
-
Hart,Curtis
, p. 112,115 (1956)
-
Gold nanoparticles supported on the periodic mesoporous organosilicas as efficient and reusable catalyst for room temperature aerobic oxidation of alcohols
Karimi, Babak,Esfahani, Farhad Kabiri
, p. 1319 - 1326 (2012)
Gold nanoparticles supported on the chan...
Ferric(III) nitrate supported on kieselguhr: A new reagent for selective oxidation of alcohols
Lou, Ji-Dong,Zhu, Long-Hua,Ma, Yi-Chun,Li, Li
, p. 3061 - 3064 (2006)
A selective and effective oxidation of a...
B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes
He, Tao,Long, Peng-Wei,Oestreich, Martin
supporting information, p. 7383 - 7386 (2020/10/12)
A hydrosilylation of vinylcyclopropanes ...
Aerobic oxidation of alcohols catalyzed by in situ generated gold nanoparticles inside the channels of periodic mesoporous organosilica with ionic liquid framework
Bigdeli, Akram,Karimi, Babak,Khodadadi Karimvand, Somaiyeh,Khorasani, Mojtaba,Safari, Ali Asghar,Vali, Hojatollah
supporting information, p. 70 - 79 (2020/06/08)
In situ generated gold nanoparticles ins...
A double-ring propyl alkone improved process for synthesizing (by machine translation)
-
Paragraph 0037-0039, (2017/03/28)
The invention discloses a double-ring im...
Synergistic catalysis within TEMPO-functionalized periodic mesoporous organosilica with bridge imidazolium groups in the aerobic oxidation of alcohols
Karimi, Babak,Vahdati, Saleh,Vali, Hojatollah
, p. 63717 - 63723 (2016/07/19)
Anchoring 2,2,6,6-tetramethylpiperidine-...
1121-37-5 Process route
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160320-40-1
3,3-dicyclopropyl-4-methoxy-4-(3-methoxyphenyl)-1,2-dioxetane
-
-
5368-81-0
methyl 3-methoxybenzoate
-
-
1121-37-5
dicyclopropyl ketone
| Conditions | Yield |
|---|---|
|
In
toluene;
Yield given. Yields of byproduct given;
Heating;
|
-
-
83313-92-2
2-acetoxy-5,5-dicyclopropyl-2-methyl-Δ3 -1,3,4-oxadiazoline
-
-
108-24-7
acetic anhydride
-
-
83313-95-5
(E)-1,4-dichloro-1-cyclopropyl-1-butene
-
-
83313-94-4
1-acetoxyethyl cyclopropylidenecyclopropylmethyl ether
-
-
75-36-5
acetyl chloride
-
-
431-03-8
dimethylglyoxal
-
-
1121-37-5
dicyclopropyl ketone
| Conditions | Yield |
|---|---|
|
With
tetrachloromethane;
at 79.5 ℃;
for 72h;
Rate constant;
Mechanism;
Product distribution;
other oxadiazoline;
|
50 % Spectr.
72 % Spectr. 9 % Spectr. 20 % Spectr. 20 % Spectr. |
1121-37-5 Upstream products
-
40624-07-5
1,7-dichloro-4-heptanone
-
41886-92-4
(Bromcyclopropylmethylen)cyclopropan
-
64-17-5
ethanol
-
87639-44-9
4-cyclopropylbut-3-yn-1-yl triflate
1121-37-5 Downstream products
-
14300-33-5
dicyclopropylmethanol
-
18895-50-6
dicyclopropylmethylcarbinol
-
5685-47-2
Bis(cyclopropyliden)methan
-
17206-84-7
ethyl 3-hydroxy-3,3-dicyclopropylpropanoate
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