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PERFLUORO-TERT-BUTANOL

  • CAS：2378-02-1
  • purity：99%
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Factory Sells Best Quality PERFLUORO-TERT-BUTANOL 2378-02-1 with GMP standards

  • Molecular Formula: C4H F9 O
  • Molecular Weight: 236.037
  • Appearance/Colour: clear colorless liquid 
  • Vapor Pressure: 5.19 psi ( 20 °C) 
  • Melting Point: -17°C 
  • Refractive Index: n20/D 1.3(lit.) 
  • Boiling Point: 45 °C(lit.)
     
  • PKA: 7.05±0.53(Predicted) 
  • Flash Point: 5.1°C 
  • PSA： 20.23000 
  • Density: 1.67g/cm3 
  • LogP: 2.40440 

PERFLUORO-TERT-BUTANOL(Cas 2378-02-1) Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 57, p. 1124, 1992 DOI: 10.1021/jo00030a018

General Description

Nonafluoro-tert-butyl alcohol is also referred as perfluorotertiarybutanol and ′artificial blood′.

InChI:InChI=1/C4HF9O/c5-2(6,7)1(14,3(8,9)10)4(11,12)13/h14H

2378-02-1 Relevant articles

-

Dear,R.E.A.

, p. 361 - 362 (1970)

-

Monitoring of biological one-electron reduction by 19F NMR using hypoxia selective activation of an 19F-labeled indolequinone derivative

Tanabe, Kazuhito,Harada, Hiroshi,Narazaki, Michiko,Tanaka, Kazuo,Inafuku, Kenichi,Komatsu, Hirokazu,Ito, Takeo,Yamada, Hisatsugu,Chujo, Yoshiki,Matsuda, Tetsuya,Hiraoka, Masahiro,Nishimoto, Sei-Ichi

, p. 15982 - 15983 (2009)

(Chemical Equation Presented) Biological...

Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations

Bauer, Matthias,Cronin, Steve P.,Dyballa, Michael,Estes, Deven P.,Li, Zheng,Maier, Sarah,Nowakowski, Michal,Vu Dinh, Manh-Anh

, p. 1751 - 1757 (2021/06/28)

Platinum hydride species catalyze a numb...

A janus-headed lewis superacid: Simple access to, and first application of Me3Si-F-Al(ORF)3

Rohde, Michael,Muller, Lutz O.,Himmel, Daniel,Scherer, Harald,Krossing, Ingo

supporting information, p. 1218 - 1222 (2014/04/03)

Upon reaction of gaseous Me3SiF with the...

The Al(ORF)3/H2O/phosphane [RF = C(CF3)3] System - Protonation of phosphanes and absolute bronsted acidity

Kraft, Anne,Possart, Josephine,Scherer, Harald,Beck, Jennifer,Himmel, Daniel,Krossing, Ingo

, p. 3054 - 3062 (2013/07/27)

The synthesis of the classical, neutral ...

Hydrogen bonding between solutes in solvents octan-1-ol and water

Abraham, Michael H.,Gola, Joelle M. R.,Cometto-Muniz, J. Enrique,Acree, William E.

experimental part, p. 7651 - 7658 (2011/02/25)

The 1:1 equilibrium constants, K, for th...

2378-02-1 Process route

nonafluoro-tert-butyl trifluoromethanesulfinate
52225-54-4

nonafluoro-tert-butyl trifluoromethanesulfinate

Carbonyl fluoride
353-50-4

Carbonyl fluoride

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
Conditions Yield
byproducts: SO2; hydrolyzes in moist air at 25°C;
C<sub>15</sub>H<sub>9</sub>AlF<sub>28</sub>O<sub>3</sub>Si

C15 H9 AlF28 O3 Si

<i>tert</i>-butyl alcohol
75-65-0

tert -butyl alcohol

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol
2378-02-1

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

C<sub>15</sub>H<sub>10</sub>AlF<sub>27</sub>O<sub>4</sub>Si

C15 H10 AlF27 O4 Si

Conditions
Conditions Yield
In dichloromethane; dichloromethane-d2; at -30 - 20 ℃; Inert atmosphere; Schlenk technique; Glovebox;

2378-02-1 Upstream products

  • 7594-49-2
    7594-49-2

    1,1,1-trichloro-3,3,3-trifluoro-2-(trifluoromethyl)propan-2-ol

  • 353-50-4
    353-50-4

    Carbonyl fluoride

  • 81290-20-2
    81290-20-2

    (trifluoromethyl)trimethylsilane

  • 2809-92-9
    2809-92-9

    nanofluoro-tert-butylamine

2378-02-1 Downstream products

  • 24165-10-4
    24165-10-4

    F-tert.-Butyltrifluoracetat

  • 186493-82-3
    186493-82-3

    F-tert-Butyl ethyl ether

  • 26842-85-3
    26842-85-3

    bis(nonafluoro-tert-butyl) peroxide

  • 75-46-7
    75-46-7

    trifluoromethan

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