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Quality products?make an important contribution to long-term revenue and profitability. Chinese Manufacturer Supply DL-alpha-Methylbenzylamine 618-36-0 On Stock with Competitive Price
1.What is the DL-alpha-Methylbenzylamine ?
α-Methylbenzylamine can be used as a reactant for the synthesis of dihydro-5H-dibenz[c,e]azepinium salts by reacting with racemic biphenol derivatives.
-
-
98-86-2
acetophenone
-
-
98-85-1,13323-81-4
1-Phenylethanol
-
-
618-36-0
rac-methylbenzylamine
| Conditions | Yield |
|---|---|
|
Hydrogenation;
|
-
-
98-86-2
acetophenone
-
-
98-85-1,13323-81-4
1-Phenylethanol
-
-
618-36-0
rac-methylbenzylamine
| Conditions | Yield |
|---|---|
|
With
ammonium chloride; ammonia; hydrogen;
palladium;
In
ethanol;
at 50 ℃;
for 5h;
|
82%
15% |
|
With
ammonium iodide; sodium tetrahydroborate;
In
isopropyl alcohol;
at 20 - 30 ℃;
|
20%
70% |
|
acetophenone;
With
(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; 1,2-bis-(diphenylphosphino)ethane;
In
dodecane; toluene;
at -5 ℃;
for 0.5h;
under 6750.68 - 7500.75 Torr;
Autoclave;
With
hydrogen;
In
dodecane; toluene;
at 120 ℃;
for 18h;
under 30003 Torr;
Reagent/catalyst;
Pressure;
chemoselective reaction;
Acidic conditions;
|
21%
32% |
|
With
ammonia; hydrogen;
bis(1,5-cyclooctadiene)diiridium(I) dichloride; 2,2'-bis[[bis(3-sulfophenyl)phosphino]methyl]-4,4',7,7'-tetrasulfo-1,1'-binaphthyl octasodium salt;
In
water; toluene;
at 130 ℃;
for 13h;
under 34503.5 Torr;
Product distribution / selectivity;
|
|
|
With
ammonium formate;
In
methanol;
at 70 ℃;
for 1.5h;
Inert atmosphere;
|
|
|
With
ammonium formate;
In
methanol;
at 70 ℃;
for 1.5h;
Inert atmosphere;
|
|
|
With
aluminium(III) triflate; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; hydrogen; 1,2-bis-(diphenylphosphino)ethane;
In
toluene;
at 120 ℃;
for 16h;
Reagent/catalyst;
Autoclave;
|
74 %Chromat.
5 %Chromat. |
|
With
(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; hydrogen; 1,2-bis-(diphenylphosphino)ethane;
In
toluene;
at 120 ℃;
for 16h;
Autoclave;
|
21 %Chromat.
32 %Chromat. |
|
With
ammonium hydroxide; palladium on activated carbon; hydrogen;
at 50 ℃;
for 20h;
under 7500.75 Torr;
Autoclave;
|
53 %Chromat.
46 %Chromat. |
|
With
ammonium hydroxide; Ir/C; hydrogen;
at 50 ℃;
for 20h;
under 7500.75 Torr;
Autoclave;
|
49 %Chromat.
30 %Chromat. |
2.What is the CAS number for DL-alpha-Methylbenzylamine ?
The CAS number of DL-alpha-Methylbenzylamine is 618-36-0.
More information of DL-alpha-Methylbenzylamine 618-36-0 are:
|
CAS?Number |
618-36-0 |
|
Density |
0.957 g/cm3 |
|
Melting Point |
-65 °C |
|
Boiling Point |
183.007 °C at 760 mmHg |
|
Flash Point |
75.803 °C |
|
Vapor Pressure |
0.7 hPa (20 °C) |
|
Refractive Index |
n20/D 1.526(lit.) |
|
HS CODE |
29214980 |
|
Pka |
9.04±0.10(Predicted) |
3.What are another words for DL-alpha-Methylbenzylamine ?
Synonyms?for?DL-alpha-Methylbenzylamine 618-36-0:Benzylamine, a-methyl-, dl- (5CI);(1-Aminoethyl)benzene;(RS)-1-Phenylethylamine;(RS)-α-Methylbenzylamine;1-Amino-1-phenylethane;1-Phenyl-1-ethanamine;1-Phenylethanamine;1-Phenylethylamine;APEA;DL-1-Phenylethylamine;DL-α-Methylbenzylamine;DL-α-Phenylethylamine;Ethanamine, 1-phenyl-;NSC 8391;dl-α-Phenethylamine;α-Aminoethylbenzene;α-Methylbenzenemethanamine;α-Methylbenzylamine;α-Phenethylamine;
4.What is the molecular formula of DL-alpha-Methylbenzylamine?
The chemical formula of ?DL-alpha-Methylbenzylamine is?C8H11N which containing 8 Carbon atoms,11 Hydrogen atoms and 1 Nitrogen atoms,and the molecular weight of??DL-alpha-Methylbenzylamine?is 121.182.
5.What is DL-alpha-Methylbenzylamine (618-36-0) used for?
DL-alpha-Methylbenzylamine, also known as α-Methylbenzylamine, is a phenylethylamine derivative that is ethylamine substituted by a phenyl group at position 1. It is a liquid chemical compound and serves as a nitrogen source, widely used as a representative substrate to study the chemo-enzymatic kinetic resolution of primary amines.
InChI:InChI=1/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3
Relevant articles related to DL-alpha-Methylbenzylamine:
|
Article |
Source |
|
Optimizing the deprotection of the amine protecting p-methoxyphenyl group in an automated microreactor platform |
Koch, Kaspar,Van Weerdenburg, Bram J.A.,Verkade, Jorge M.M.,Nieuwland, Pieter J.,Rutjes, Floris P.J.T.,Van Hest, Jan C.M. , p. 1003 - 1006 (2009) |
|
Iridium-Catalyzed Hydroiodination and Formal Hydroamination of Olefins with N-Iodo Reagents and Molecular Hydrogen: An Umpolung Strategy |
Wen, Jialin,Yang, Huaxin,Zhang, Xumu,Zhang, Zhihan,Zhou, Yang , p. 1842 - 1847 (2022/03/14) |
6.Buy DL-alpha-Methylbenzylamine with the best price .
HuiDe Tech Industrial Co., Ltd. is a quality supplier of DL-alpha-Methylbenzylamine. Our main goal is customer satisfaction. Contact us to negotiate the best price for your business on DL-alpha-Methylbenzylamine 618-36-0.
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